Synthesis and Structural-chemical Studied of Adduct of Coordination Supramolecular Porous Polymer Hexaaquatribenzene-1,2,4,5- Teacarbonato-tetrairon(iii) with Dipyridyl

  • B. T. Usubaliyev 1 Research Institute of Geotechnological Problems of Oil, Gas and Chemistry of Azerbaijan State University of Oil and Industry, Baku State University, Azerbaijan, AZ 1010, D.Aliyeva str. 227
  • D. B. Taghiyev 2 Academician M.Nagiyev Institute of Catalysis and Inorganic Chemistry of Azerbaijan National Academy of Sciences
  • M. K. Munshiyeva 2 Academician M.Nagiyev Institute of Catalysis and Inorganic Chemistry of Azerbaijan National Academy of Sciences
  • G. M. Aliyeva 2 Academician M.Nagiyev Institute of Catalysis and Inorganic Chemistry of Azerbaijan National Academy of Sciences
  • F. B. Aliyeva 2 Academician M.Nagiyev Institute of Catalysis and Inorganic Chemistry of Azerbaijan National Academy of Sciences
  • A. K. Rzayeva 1 Department of Physics, Government College University Faisalabad, 38000 Faisalabad, Pakistan
  • M. M. Hasanova 1 Department of Physics, Government College University Faisalabad, 38000 Faisalabad, Pakistan
  • P. S. Safarova 1 Department of Physics, Government College University Faisalabad, 38000 Faisalabad, Pakistan
  • G. Z. Mammadova 2 Department of Physics, Lahore University of Management Sciences, Lahore 54000, Pakistan
DOI: https://doi.org/10.18282/mpc.v1i3.583
Keywords: Compound, Adduct, Thermal Destruction, Chemical Formula, Crystal Structure

Abstract

An α, α′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acid-ic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe4(C6H2(COO)4)3(dpy)2 (dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.

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Published
2020-05-22
How to Cite
Usubaliyev, B. T., Taghiyev, D. B., Munshiyeva, M. K., Aliyeva, G. M., Aliyeva, F. B., Rzayeva, A. K., Hasanova, M. M., Safarova, P. S., & Mammadova, G. Z. (2020). Synthesis and Structural-chemical Studied of Adduct of Coordination Supramolecular Porous Polymer Hexaaquatribenzene-1,2,4,5- Teacarbonato-tetrairon(iii) with Dipyridyl. Materials Physics and Chemistry, 2(1), 23-28. https://doi.org/10.18282/mpc.v1i3.583
Issue
Vol. 2 No. 1 (2020)
Section
Original Research Articles

Copyright (c) 2020 B. T. Usubaliyev et al.

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