Synthesis and Structural-chemical Studied of Adduct of Coordination Supramolecular Porous Polymer Hexaaquatribenzene-1,2,4,5- Teacarbonato-tetrairon(iii) with Dipyridyl

B. T. Usubaliyev; D. B. Taghiyev; M. K. Munshiyeva; G. M. Aliyeva; F. B. Aliyeva; A. K. Rzayeva; M. M. Hasanova; P. S. Safarova; G. Z. Mammadova

doi:10.18282/mpc.v1i3.583

B. T. Usubaliyev 1 Research Institute of Geotechnological Problems of Oil, Gas and Chemistry of Azerbaijan State University of Oil and Industry, Baku State University, Azerbaijan, AZ 1010, D.Aliyeva str. 227
D. B. Taghiyev 2 Academician M.Nagiyev Institute of Catalysis and Inorganic Chemistry of Azerbaijan National Academy of Sciences
M. K. Munshiyeva 2 Academician M.Nagiyev Institute of Catalysis and Inorganic Chemistry of Azerbaijan National Academy of Sciences
G. M. Aliyeva 2 Academician M.Nagiyev Institute of Catalysis and Inorganic Chemistry of Azerbaijan National Academy of Sciences
F. B. Aliyeva 2 Academician M.Nagiyev Institute of Catalysis and Inorganic Chemistry of Azerbaijan National Academy of Sciences
A. K. Rzayeva 1 Department of Physics, Government College University Faisalabad, 38000 Faisalabad, Pakistan
M. M. Hasanova 1 Department of Physics, Government College University Faisalabad, 38000 Faisalabad, Pakistan
P. S. Safarova 1 Department of Physics, Government College University Faisalabad, 38000 Faisalabad, Pakistan
G. Z. Mammadova 2 Department of Physics, Lahore University of Management Sciences, Lahore 54000, Pakistan

Ariticle ID: 583

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DOI: https://doi.org/10.18282/mpc.v1i3.583

Keywords: Compound, Adduct, Thermal Destruction, Chemical Formula, Crystal Structure

Abstract

An Î±, Î±â€²-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acid-ic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe4(C6H2(COO)4)3(dpy)2 (dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.

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