Reparation and properties of ceramifiable ethylene propylene diene monomer

  • liangdian Liu
Ariticle ID: 200
174 Views, 15 PDF Downloads
Keywords: Ethylene Propylene diene monomer (EPDM), chopped polyimide fiber, Composites thermal stability,

Abstract

The ceramifiable ethylene propylene diene monomer (EPDM) composites with different fiber contents

were prepared by taking EPDM as the matrix , Kaolin and talc as the functional fillers , Aluminum Hydroxide as the

Flame Retardant , The and the chopped polyimide (PI) fiber as the reinforcement. The effects of chopped polyimide fiberson thetensile properties,Thermal Stability and microstructure of ceramifiable PI Fiberkaolin-talc-akoh)3/ EPDM (PKTA/EPDM) composites were investigated, and theceramicization Mechanism of chopped polyimide fiber reinforced composites was analyzed. The results show, the tensile strength of the composites decreases with the increasing of chopped Imide fibers. When the chopped PI fibers are less than : [mass ratio to

EPDM ),Mechanical properties of the composites are. The ceramifiable PKTA/EPDM composites can be ceramicized after pyrolysis at 800-1 100C. The addition of 4 : ,-8 : mass ratio to EPDM chopped poly- imide fibers can effectively keep the shape stability of the Composites after pyrolysis at the-1 0 C , and thebending strength of the ceramic productf I between 6-18 MPa. The results of thermal analysis show that the thermal

LIU L d,qin y,song J q,et Al Preparation and properties of ceramifiable ethylene propylene diene monomer rubber Composites reinforced with the chopped polyimide iibers[j]. Acta materiae Compositae sinica,2017, : 2800-2809 (in Chinese).

and SEM Analysis I ndicate that the pyrolysis and carbonization of the chopped PI fibers in the char layer form the

Structure of fiber^reinforced char layer. The PI fiber reinforced structure contributes to obtaining the well-shaped EPDM Composites.

References

Pedzich z,ziabka M,anyszka r,et al. silicon-basing ceramizable composites containing long iibers[j]. Journal of materials science and chemical Engineering, 2015 , 1 (5 ):43-48.

anyszka R,bielinski D M,pedzich Z,et al. Influence of Surface-modified montmorillonites on properties of Il- iconerubberbased ceramizable composites [J]. Journal of thermal analysis & calorimetry, 2015,119 (1): 111-121.

D,grzegorz P,zbigniew p,et al. ceramizable Silicone composites destined for covers of electrical cables : pola-nal,EP20140460014 [P]. 2014-09-17.

anyszka R,pedzich Z,bielinski D m,et al. ceramizable Silicone rubbei^based composites [J]. Advances in Science & Technology, % ,1:82-88.

Imiela M,antszka R,bielinski D m,et al. Effect of carbon fibers on thermal properties and mechanical

strength of ceramizable composites based on silicone rubber [J]. Journal of thermal analysis & calorimetry, 2016, 124

(1): 197-203.

ALEXANDER G,cheng Y b,burford rp,etal ce-ramifying composition for fire protection: /b20> U. S. Patent 8, 409, 479[p ]. 2013-4-2.

Huang Zhixiong , Qin , Lao Zhirong , , and so on . a kind of ceramic high carbon polymer base

Composites and their preparation methods : 103058632. a[p]. 2013-04-24. HUANG Z X, QIN Y, RAO Z L, et al. Ceramifying high carbon based polymer composites:103058632. A[P]. 201304-24 (in Chinese).

THOMAS t h,kendrick T C Thermal Analysis of Pol- ysiloxanes II: Thermal vacuum degradation of pol-ysiloxanes with different substituents on Silicon and in the main siloxane

Chain[j]. Journal of polymerScience: part a-2-polymer Physics , 1970 , 8 ): 1823-1830.

Hshieh F. Shielding effects of silica-ash layer on the combustion of: silicones and their possi BLE applications on the fire retardancy of organic polymers [J]. Fire and Materials, 1998, (2 ): 69-76.

Radhakrishnan T S. New method for evaluation of Ki netic parameters and mechanism of degradation from Py-roly¬- SIS-GC St Udies: Thermal degradation of Polydimethylsiloxanes [J]. Journal of Applied PolymerScience, 1999 ,(3):

-450

CAMINO G , lomakin S M , Lazzari M. Polydimethyl-siloxane Thermal Degradation : Part 1-kinetic aspects [J]. Polymer,2001,42 (6 ): 2395-2402.

CAMINO G , lomakin S M , lageard M Thermal

polydimethylsiloxane degradation : Part 2-the degradation mechanisms[j]. Polymer,2002,43 (7) : 2011-2015.

Deshpande G , Rezac¬M E. Kinetic aspects of ther mal degradation of poly (dimethyl siloxane) and poly (dimethy L diphenylsiloxane) [J]. Polymer degradation and Stabili-ty, 2002 (1): 17-24.

Hanul G , SIMON G P , CHENG Y B. Preferential orientation of Muscovite in ceramifiable silicone composites [J]. Materials science and Engineering A,??, 398 (1-2 ): 180-187.

Mansourij , BURFORD R P , CHENG Y B , et al. Formation of strong ceramified ash from silicone-based composi- tions[J]. Journal of Materialsscience, all , ():

-5749

MANSOURI J , woodc A , Robertsk , etal Investigation of the ceramifying process of modified silicone-silicate compositions [J]. Journal of Materialsscience, 2007 ,

: 6046-6055.

Mansourij , BURFORD R P , CHENG Y B. pyrolysis behaviour of silicone-based ceramifying Composites[j]. Ma-terials science and Engineering A,2006, 425 (1) : 7- ,

Hanu L G , SIMON G P , CHENG Y B. Thermal stability and flammability of silicone polymer composites[j]. Polymer degradation and stability,2006, 91 (6) : 1373-1379.

Meng , Zhang Guangwu , Bear Dream , , and so on . Glass to ceramic silicone rubber base compound effect of ma-terial on high temperature performance []. Journal of Composite Materials , 2016, (): 2205-2214

MENG P , ZHANG G W , Xiong M , et al. Effect of Glass frits on high-temperature resistance properties of ceramifiable silicone Rubber Matrix Co Mposites [J]. Acta materiae com-positae sinica,2016, Ten: 2205-2214 (in Chinese).

Qin , Lao Zhirong , Liu Huijuan , , and so on . ceramic phenolic composites ablation heat insulation Performance Study []. FRP / Composites , % (S1): 52-55.

QIN Y , RAO ZL , LIU H J , etal The studying of ablation and heat insulation properties of ceramifiable phenolic com posite[j].¬ Fiber reinforced plastics/composites,,2012cs1): 52-55 (in Chinese).

Kiangwan , Wu Bulin . Exploration of ceramic æ‘» in plastics under combustion conditions

[]. Plastics Industry , 2008:167-169.

Iianj,wu B L. Exploration of ceramic-like Flame retard ant additive for plastics [J].¬ Plastics Industry, 2008 (+): 167-169 (in Chinese).

al-hassany Z, GENOVESE a,shanks R A. Fire-retardant and Fire-barrier poly (vinyl acetate) composites for Seala NT application [J]. Express Polymer Letters, ,, 4 (2): 79-93.

SHAO II , WANG T,zhang q.ceramfying ire-resistant polyethylene composites[j]. Advanced composites letters,

, (5): 175-179.

DI H w,deng c,li R M,et al. A novel EVA composite with simultaneous flame retardation and ceramifiable capaci-ty []. RSC advances,2015, 5 (3): 51248-51257.

How to Cite
Liu, liangdian. (1). Reparation and properties of ceramifiable ethylene propylene diene monomer. Composite Materials Research, 6(2). https://doi.org/10.1828/cmr.v6i2.200
Section
Articles